Linear and non-linear optical response properties of β-enamino ketones

被引：12

作者：

Misra, Ramprasad ^{[1
]}

Bhattacharyya, S. P. ^{[1
]}

Maity, D. K. ^{[2
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Phys Chem, Kolkata 700032, W Bengal, India

[2] Bhabha Atom Res Ctr, Chem Grp, Theoret Chem Sect, Bombay 400085, Maharashtra, India

来源：

CHEMICAL PHYSICS LETTERS | 2008年 / 458卷 / 1-3期

关键词：

D O I：

10.1016/j.cplett.2008.04.102

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

beta-Enamino ketone (I) is experimentally shown to have a strong red shifted absorption maximum in its electronic spectrum in polar solvents and theoretically predicted to have high quadratic hyperpolarizability. Electron releasing and withdrawing substituents in the para position of the phenyl ring affect the NLO response indicating ICT as one of the controlling processes. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：54 / 57

页数：4

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