Discrete metal complexes of two multiply armed ligands

被引：26
|
作者：
Al-Mandhary, Muna R. A.
Fitchett, Christopher M.
Steel, Peter J. [1 ]
机构：
[1] Univ Canterbury, Dept Chem, Christchurch 8020, New Zealand
[2] Sultan Qaboos Univ, Coll Sci, Al Khoud 123, Oman
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 2006年 / 59卷 / 05期
关键词：
D O I：
10.1071/CH06116
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The syntheses and metal complexes of 1,2,4,5-tetrakis(8-quinolyloxymethyl) benzene 1 and hexakis(8-quinolyloxymethyl) benzene 2 are described. X-Ray crystal structures are reported of the free ligand 1, a binuclear silver(I) and a tetranuclear copper(I) complex of 1, as well as a binuclear cobalt(II) and trinuclear palladium(II) and silver(I) complexes of 2. Within these discrete metal complexes the ligands are found to adopt a range of coordination modes, with considerable variation in the relative orientations of the ligand arms as a result of the flexibility imparted by the CH2O linker units.
引用
收藏
页码：307 / 314
页数：8
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