Relationship between alkyl chain length and adsorption energy of N-alkyl-N,N-dialkyl-3-(siloxanyl)propylammonium bromides at the mercury/electrolyte interface

被引：2
|
作者：
Retter, U
Schmaucks, G
Klinger, R
机构：
[1] Ba. fur Materialforschung und -Pruf., D-12489 Berlin
[2] D-15366 Birkenstein
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1996年 / 180卷 / 01期
关键词：
adsorption; siloxanes; alkyl chain length; mercury/electrolyte interface;
D O I：
10.1006/jcis.1996.0292
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The influence of the variation in alkyl chain length at the nitrogen atom of ammonium group-containing siloxane surfactants on the adsorption energy and lateral interaction energy at the mercury/electrolyte interface has been investigated by means of the concentration dependence of the differential capacity, The results show that for various siloxane backbones, successive addition of methylene groups to the alkyl leads to a corresponding successive increase in the adsorption energy. (C) 1996 Academic Press, Inc.
引用
收藏
页码：218 / 224
页数：7
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