Selective water sorbents for multiple applications .2. CaCl2 confined in micropores of silica gel: Sorption properties

被引：85
|
作者：
Aristov, YI [1 ]
Tokarev, MM [1 ]
Restuccia, G [1 ]
Cacciola, G [1 ]
机构：
[1] INST ENERGY TRANSFORMAT & ACCUMULAT,MESSINA,ITALY
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1996年 / 59卷 / 02期
关键词：
vapor sorption; calcium chloride; silica gel micropores;
D O I：
10.1007/BF02068131
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Water sorption isobars, isochores and isotherms for CaCl2 confined to a microporous silica gel appear to differ from those measured for mesoporous host matrix. The sorption equilibrium was found to be of the bivariant nature typical for liquid salt solutions. No indication for solid hydrate formation was recorded The results obtained evidence a significant change in the thermodynamic properties of the solution due to its confinement to the micropores. This change is qualitatively discussed on the basis of the classical model of strong electrolyte dilute solutions.
引用
收藏
页码：335 / 342
页数：8
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