Proton-transfer supramolecular salts of D-/L-tartaric acid and 1-(2-Pyrimidyl)piperazine

被引：22

作者：

Ding, Xue-Hua ^{[1
]}

Li, Yong-Hua ^{[1
]}

Wang, Shi ^{[1
]}

Huang, Wei ^{[1
,2
]}

机构：

[1] Nanjing Univ Posts & Telecommun, Inst Adv Mat IAM, Key Lab Organ Elect & Informat Displays KLOEID, Nanjing 210046, Jiangsu, Peoples R China

[2] Nanjing Univ Technol, Inst Adv Mat, Jiangsu Singapore Joint Res Ctr Organ Bioelect &, Nanjing 211816, Jiangsu, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1062卷

关键词：

Proton-transfer; Supramolecular salts; Hydrogen bonding; Supramolecular synthons; 3D framework; HYDROGEN-BOND; NONCOVALENT SYNTHESIS; TARTRATE; FERROELECTRICS; CHEMISTRY; COMPLEX;

D O I：

10.1016/j.molstruc.2013.12.054

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ionic supramolecular salts 1 and 2 were prepared by single-proton transfer reactions between 1-(2-pyrimidyl)piperazine and D-/L-tartaric acid. An interesting feature in the tartrate is the head-to-tail arrangement and very wide range of anionic substructures observed through hydrogen-bonding interactions, including ring motifs, infinite double zigzag chain and three-dimensional supramolecular framework. Thermal analysis revealed that salts 1 and 2 undergo an irreversible phase transition at about 158 degrees C, which is ascribed to the loss of water molecule. The temperature- and frequency-dependent dielectric constants in 2 suggested a low-frequency thermal fluctuation above 100 degrees C. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：61 / 67

页数：7

共 50 条

[41] One-Dimensional Hydrogen-Bonded Structures in the 1:1 Proton-Transfer Salts of 4,5-Dichlorophthalic Acid with the Aliphatic Lewis Bases Diisopropylamine and Hexamethylenetetramine
Graham Smith
Urs D. Wermuth
Journal of Chemical Crystallography, 2010, 40 : 207 - 212
[42] One-Dimensional Hydrogen-Bonded Structures in the 1:1 Proton-Transfer Salts of 4,5-Dichlorophthalic Acid with the Aliphatic Lewis Bases Diisopropylamine and Hexamethylenetetramine
Smith, Graham
Wermuth, Urs D.
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2010, 40 (03) : 207 - 212
[43] Synthesis of hyperbranched 2,5-anhydro-D-glucitol by proton-transfer cyclopolymerization of 1,2:5,6-dianhydro-D-mannitol
Imai, T
Satoh, T
Kaga, H
Kaneko, N
Kakuchi, T
MACROMOLECULES, 2003, 36 (17) : 6359 - 6363
[44] 2,3-Dimethoxy-10-oxostrychnidinium 3-carboxybenzoate trihydrate:: the 1:1 proton-transfer compound of brucine with isophthalic acid
Smith, G
Wermuth, UD
Young, DJ
White, JM
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : O1553 - O1555
[45] Supramolecular association in proton-transfer adducts containing benzamidinium cations. II. Concomitant polymorphs of the molecular salt of 2,6-dimethoxybenzoic acid with benzamidine
Irrera, Simona
Ortaggi, Giancarlo
Portalone, Gustavo
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2012, 68 : O447 - +
[46] Enantioselective synthesis of (1R)-1-(hydroxymethyl)-2-acetyl-1,2,3,4-tetrahydro-β-carboline from L-(+)-tartaric acid
Arazny, Z
Czarnocki, Z
Wojtasiewicz, K
Maurin, JK
TETRAHEDRON-ASYMMETRY, 2000, 11 (13) : 2793 - 2800
[47] Hydrogen Bonded Supramolecular Association in Organic Acid–Base Salts: Crystal Structures of Four Proton-Transfer Complexes Assembled from 2-Amino-4-methylpyridine with 2-Chloro, 4-Chloro, 3-Methyl and 4-Methylbenzoic Acid
Nuridayanti Che Khalib
Kaliyaperumal Thanigaimani
Suhana Arshad
Ibrahim Abdul Razak
Journal of Chemical Crystallography, 2014, 44 : 555 - 571
[48] Novel stereoselective synthesis of 1-(β-D- and α-L-glycopyranosyl)-5-methyl-1H-1,2,4-triazoles
Yu, JX
Li, ZJ
Lu, WJ
Zhang, S
Cai, MS
TETRAHEDRON-ASYMMETRY, 2003, 14 (17) : 2507 - 2513
[49] Hydrogen bonding in the anhydrous 1:1 proton-transfer compounds of isonipecotamide with nitro-substituted benzoic acids: the salts of the three isomeric mononitrobenzoic acids and of 3,5-dinitrobenzoic acid
Smith, Graham
Wermuth, Urs D.
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2010, 66 : O614 - O618
[50] Hydrogen Bonded Supramolecular Association in Organic Acid-Base Salts: Crystal Structures of Four Proton-Transfer Complexes Assembled from 2-Amino-4-methylpyridine with 2-Chloro, 4-Chloro, 3-Methyl and 4-Methylbenzoic Acid
Khalib, Nuridayanti Che
Thanigaimani, Kaliyaperumal
Arshad, Suhana
Razak, Ibrahim Abdul
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2014, 44 (11-12) : 555 - 571

← 1 2 3 4 5 →