Catalytic activation of C-H and C-C bonds of allylamines via olefin isomerization by transition metal complexes

被引：46

作者：

Jun, CH ^{[1
]}

Lee, H ^{[1
]}

Park, JB ^{[1
]}

Lee, DY ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 13期

关键词：

D O I：

10.1021/ol990357b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The metal-catalyzed reaction of olefins with allylamines bearing coordination sites (2-pyridyl groups) was studied. With Ru-3(CO)(12) as catalyst, activation of C-H bonds led to the formation of ketimines that were hydrolyzed to give asymmetric ketones. With [(C8H14)(2)RhCl](2), both C-H and C-C bonds were activated and symmetric ketones were formed on hydrolysis. The reaction involves double bond migration of the allylamine to form an aldimine.

引用

页码：2161 / 2164

页数：4

共 50 条

[1] ACTIVATION OF C-H AND C-C BONDS IN ETHYLENE AND PIPERYLENE CATALYTIC REACTIONS
BELOV, GP
DZHABIEV, TS
KOLESNIKOV, IM
JOURNAL OF MOLECULAR CATALYSIS, 1982, 14 (01): : 105 - 112
[2] MERCAT CHEMISTRY - FORMING C-C BONDS VIA C-H ACTIVATION
CRABTREE, RH
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 184 - INOR
[3] Activation of C-H bonds by metal complexes
Shilov, AE
Shul'pin, GB
CHEMICAL REVIEWS, 1997, 97 (08) : 2879 - 2932
[4] Activation of C-H bonds by metal complexes
N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 117977 Moscow, Russia
Chem. Rev., 8 (2879-2932):
[5] Catalytic activation of C-C and C-H bonds in alkanes under mild conditions
V. M. Akhmedov
Catalysis in Industry, 2014, 6 (4) : 253 - 259
[6] Catalytic Activation of C-C and C-H Bonds in Alkanes under Mild Conditions
Akhmedov, V. M.
CATALYSIS IN INDUSTRY, 2014, 6 (04) : 253 - 259
[7] Catalytic hydrocarbon rearrangement via C-H and C-C bond activation by platinum(II) complexes
Bowring, Miriam A.
Bergman, Robert G.
Tilley, T. Don
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
[8] Early transition metals in hydroaminoalkylation: Catalytic C-C bond formation via C-H activation
Schafer, Laurel L.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
[9] THE ACTIVATION OF C-H BONDS BY SOLUBLE TRANSITION-METAL COMPLEXES
PARSHALL, GW
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 185 (MAR): : 1 - INOR
[10] Transition-Metal-Catalyzed C-H Bond Activation for the Formation of C-C Bonds in Complex Molecules
Docherty, Jamie H.
Lister, Thomas M.
Mcarthur, Gillian
Findlay, Michael T.
Domingo-Legarda, Pablo
Kenyon, Jacob
Choudhary, Shweta
Larrosa, Igor
CHEMICAL REVIEWS, 2023, 123 (12) : 7692 - 7760

← 1 2 3 4 5 →