Rhodium-Catalyzed Cross-Coupling of Alkenyl Halides with Arylboron Compounds

被引：15
|
作者：
Matsuda, Takanori [1 ]
Suzuki, Kentaro [1 ]
Miura, Norio [1 ]
机构：
[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 17期
关键词：
alkenes; boron; cross-coupling; rhodium; synthetic methods; ALPHA; BETA-UNSATURATED CARBOXYLIC-ACIDS; STEREOSELECTIVE-SYNTHESIS; CINE-SUBSTITUTION; ARYL; ARYLATION; EFFICIENT; REAGENTS; CARBON;
D O I：
10.1002/adsc.201300482
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The rhodium(I)-catalyzed reaction between arylboronic esters and excess 1,2-dichloroethene selectively afforded (2-chlorovinyl)arenes. Double arylation yielding 1,2-diarylethenes was observed when 1,2-dibromoethene was reacted with 2.5 equivalents of arylboronic acid.
引用
收藏
页码：3396 / 3400
页数：5
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