Crystal structure of the RCuZn, RAgZn and RAgAl intermetallic compounds (R = rare earth metals)

被引：26

作者：

Fornasini, ML ^{[1
]}

Iandelli, A ^{[1
]}

Merlo, F ^{[1
]}

Pani, M ^{[1
]}

机构：

[1] Univ Genoa, Dipartimento Chim & Chim Ind, I-16146 Genoa, Italy

来源：

INTERMETALLICS | 2000年 / 8卷 / 03期

关键词：

rare-earth intermetallics; phase stability; prediction;

D O I：

10.1016/S0966-9795(99)00111-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The RCuZn, RAgZn and RAgAl intermetallic compounds (R = rare earth metals) were synthesized and structurally studied by powder and single crystal X-ray diffraction. Among the 28 examined phases, YbAgAl crystallizes in the MgZn2 structure type, while all the others belong to the CeCu2 type. The usual decrease of the cell parameters from lanthanum to erbium is observed, and the clear positive deviation of the three ytterbium compounds can be imputed to Yb divalency. The application of the structural map method to the RMX compounds, where M and X are elements of the 10 to 15 groups, allows some predictions about unknown phases to be proposed. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：239 / 246

页数：8

共 50 条

[31] Volume effects in rare earth intermetallic compounds
Merlo, F., 1600, (197):
[32] Electronic structures of intermetallic rare earth compounds
Szytula, A.
Gomolka, D.
Jezierski, A.
Penc, B.
Wawrzynska, E.
Winiarski, A.
MATERIALS SCIENCE-POLAND, 2006, 24 (03): : 557 - 561
[33] Calciothermic powders of rare metals and intermetallic compounds
Kasimtsev, A., V
Levinsky, Yu, V
Yudin, S. N.
NON-FERROUS METALS, 2020, (02): : 31 - 50
[34] CRYSTAL STRUCTURE OF RARE-EARTH COBALT COMPOUNDS OF TYPE R3CO
BUSCHOW, KHJ
VANDERGO.AS
JOURNAL OF THE LESS-COMMON METALS, 1969, 18 (03): : 309 - &
[35] ELECTRONIC STRUCTURE CALCULATION ON RARE EARTH IRON BORON INTERMETALLIC COMPOUNDS.
Ching, W.Y.
Gu, Zong-Quan
Journal of the less-common metals, 1986, 126
[36] THE PREDICTION AND SYNTHESIS OF SOME NEW INTERMETALLIC COMPOUNDS BETWEEN TRANSITION-METALS AND RARE-EARTH METALS
NING, YT
ZHOU, XM
ZHEN, Y
CHEN, NY
XU, H
ZHU, JZ
JOURNAL OF THE LESS-COMMON METALS, 1989, 147 (02): : 167 - 173
[37] PREDICTION AND SYNTHESIS OF SOME NEW INTERMETALLIC COMPOUNDS BETWEEN TRANSITION METALS AND RARE-EARTH METALS.
Ning Yuan-tao
Zhou Xin-ming
Zheng Yun
Chen Nian-yi
Xu Hua
Zhu Jian-zhong
Xi You Jin Shu/Rare Metals, 1985, 4 (03): : 31 - 34
[38] CRYSTAL-FIELD SPLITTING OF SOME RARE-EARTH INTERMETALLIC COMPOUNDS WITH CU3AU STRUCTURE
GROSS, W
KNORR, K
MURANI, AP
BUSCHOW, KHJ
ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER, 1980, 37 (02): : 123 - 134
[39] Structure and Properties of the Intermetallic Alloy Based on Nickel Aluminide Microalloyed with Rare Earth Metals
Bazyleva O.A.
Arginbaeva E.G.
Shestakov A.V.
Fesenko T.V.
Inorganic Materials: Applied Research, 2019, 10 (06) : 1314 - 1324
[40] Electronic structure and volume magnetostriction of rare-earth metals and compounds
Turek, I
Rusz, J
Divis, M
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2005, 290 : 357 - 363

← 1 2 3 4 5 →