Thermal Stability of Trimolecular Cocrystallizate Based on Energy-Intensive Polynitramine CL-20 with H2O2 and H2O and its Efficiency in Solid Composites

被引：1
|
作者：
Kazakov, A., I [1 ]
Lempert, D. B. [1 ]
Nabatova, A., V [1 ]
Gorbovskii, K. G. [2 ]
Chukanov, N., V [1 ]
Ignatieva, E. L. [1 ]
Dashko, D., V [3 ]
Yanovskiy, L. S. [1 ,4 ]
机构：
[1] Russian Acad Sci, Fed Res Ctr Problems Chem Phys & Med Chem, Chernogolovka, Russia
[2] AO Samoilov Sci Res Inst Fertilizers & Insectofun, Cherepovets, Russia
[3] Tekhnolog Special Design & Technol Bur, St Petersburg, Russia
[4] Moscow MV Lomonosov State Univ, Fac Chem, Moscow, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B | 2022年 / 16卷 / 06期
关键词：
energy-intensive compounds; 2; 4; 6; 8; 10; 12-hexanitro-2; 12-hexaazaisowurtzitane; hydrogen peroxide; nonstoichiometric cocrystallisates; thermal stability; specific and effective specific impulse; HYDROGEN-PEROXIDE; KINETICS; DECOMPOSITION; ENTHALPY; NO2;
D O I：
10.1134/S1990793122060173
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The thermal stability of the solid monoclinic trimolecular complex (TMC II) formed by molecules of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20), H2O2, and H2O in a molar ratio of 2.0 : 0.8 : 0.2 is investigated by the methods of isothermal and nonisothermal calorimetry and nonisothermal gravimetry. The efficiency of TMC II with four CL-20 polymorphs (alpha, beta, gamma, and epsilon) in solid composites is compared.
引用
收藏
页码：1044 / 1052
页数：9
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