(C4H12N2)3[Ga4(OH)2(H2PO4)2(HPO4)4(PO4)2]:: a new organically templated gallium phosphate

被引：2
|
作者：
Lin, Chia-Her [1 ]
Wang, Sue-Lein [1 ]
机构：
[1] Chung Yuan Christian Univ, Dept Chem, Chungli 320, Taiwan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806045375
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The solvothermal reaction of gallium oxide with phosphoric acid in water/ethylene glycol in the presence of piperazine gave the title compound, bis(piperazinium) bis(dihydrogen-phosphato) tetra-mu(2)-hydrogenphosphato-di-mu(3)-hydroxo-di-mu(3)phosphato- tetragallate(III), (C4H12N2)(3)[Ga-4(OH)(2)(H2PO4)(2)-HPO4)(4)(PO4)(2)]. The compound is isostructural with its Fe-III analogue, and contains one-dimensional anionic chains with piperazinium cations lying between them. The tetranuclear anionic building blocks and the piperazinium cations lie on inversion centres.
引用
收藏
页码：M3289 / M3290
页数：2
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