A new formulation for quenching processes under restricted geometry conditions in the Slow Exchange Limit

被引：4
|
作者：
Sanchez, F. [1 ]
Barrios, A. [1 ]
Lopez-Lopez, M. [2 ]
Lopez-Cornejo, P. [1 ]
Bernal, E. [1 ]
Sarrion, B. [1 ]
Lebron, J. A. [1 ]
Marchena, M. [1 ]
机构：
[1] Univ Seville, Dept Phys Chem, E-41012 Seville, Spain
[2] Univ Huelva, Dept Chem Engn Phys Chem & Organ Chem, Huelva 21071, Spain
来源：
PROGRESS IN REACTION KINETICS AND MECHANISM | 2014年 / 39卷 / 02期
关键词：
restricted geometry; photochemistry; Stern-Volmer; kinetics; pseudophase model; excited state; BINDING; DNA;
D O I：
10.3184/146867814X13981545065017
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A quantitative treatment of quenching processes under restricted geometry conditions in the Slow Exchange Limit is presented. The expressions for K-SV have been obtained for this limit in some common situations that can arise in studies under restricted geometry conditions, such as an inhomogeneous quencher distribution in the solution, the presence of oxygen in solution, or the case of solutions containing a mixture of receptors. These situations have been considered and incorporated into the treatment.
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页码：151 / 170
页数：20
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