Iodine induced transformations of alcohols under solvent-free conditions

被引：36
|
作者：
Stavber, Gaj.
Zupan, Marko
Stavber, Stojan
机构：
[1] Jozef Stefan Inst, Organ & Bioorgan Chem Lab, Ljubljana 1000, Slovenia
[2] Univ Ljubljana, Fac Chem & Chem Technol, Ljubljana 1000, Slovenia
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 48期
关键词：
iodine; solvent-free; alcohols; catalyst;
D O I：
10.1016/j.tetlet.2006.09.154
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Iodine has been shown to be an efficient catalyst for transformations of alcohols under solvent-free conditions. In the presence of 5% of iodine, tertiary alcohols underwent dehydration forming the corresponding alkenes, while in the case of 2-phenylpropane-2-ol cyclodimerisation to 1,1,3-trimethyl-3-phenylindane took place. Secondary and primary benzyl alcohols under the same conditions gave the corresponding ethers. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8463 / 8466
页数：4
相关论文
共 50 条
  • [21] An Efficient Selective Oxidation of Alcohols with Zinc Zirconium Phosphate under Solvent-free Conditions
    Karimi, Hirbod
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2015, 62 (07) : 604 - 613
  • [22] Acetylation of alcohols and phenols under solvent-free conditions using copper zirconium phosphate
    Hajipour, Abdol R.
    Karimi, Hirbod
    CHINESE JOURNAL OF CATALYSIS, 2014, 35 (12) : 1982 - 1989
  • [23] Thiazolium-Based Catalysts for the Etherification of Benzylic Alcohols under Solvent-Free Conditions
    Bivona, Lucia Anna
    Quertinmont, Francois
    Beejapur, Hazi Ahmad
    Giacalone, Francesco
    Buaki-Sogo, Mireia
    Gruttadauria, Michelangelo
    Aprile, Carmela
    ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (04) : 800 - 810
  • [24] An efficient selective oxidation of alcohols with iron zirconium phosphate under solvent-free conditions
    Abdol Reza Hajipour
    Hirbod Karimi
    Amir Masti
    Monatshefte für Chemie - Chemical Monthly, 2016, 147 : 413 - 423
  • [25] An efficient selective oxidation of alcohols with iron zirconium phosphate under solvent-free conditions
    Hajipour, Abdol Reza
    Karimi, Hirbod
    Masti, Amir
    MONATSHEFTE FUR CHEMIE, 2016, 147 (02): : 413 - 423
  • [26] Synthesis of β-amino alcohols using MgO as a new catalyst under solvent-free conditions
    Hossein-Sarvari, Mona
    CANADIAN JOURNAL OF CHEMISTRY, 2008, 86 (01) : 65 - 71
  • [27] Acetylation of alcohols and phenols under solvent-free conditions using iron zirconium phosphate
    Hajipour, Abdol R.
    Karimi, Hirbod
    Masti, Amir
    CHINESE JOURNAL OF CATALYSIS, 2015, 36 (04) : 595 - 602
  • [28] Iodine-catalyzed efficient synthesis of chalcones by grinding under solvent-free conditions
    Wang, Hongshe
    Zeng, June
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2009, 87 (09): : 1209 - 1212
  • [29] Highly efficient acylation of alcohols, amines and thiols under solvent-free and catalyst-free conditions
    Ranu, BC
    Dey, SS
    Hajra, A
    GREEN CHEMISTRY, 2003, 5 (01) : 44 - 46
  • [30] Facile reduction of carboxylic acids to primary alcohols under catalyst-free and solvent-free conditions
    Harinath, Adimulam
    Bhattacharjee, Jayeeta
    Panda, Tarun K.
    CHEMICAL COMMUNICATIONS, 2019, 55 (10) : 1386 - 1389
12345