Charge-tunable indium-organic frameworks built from cationic, anionic, and neutral building blocks

被引:40
|
作者
Bu, Fei [1 ]
Lin, Qipu [1 ]
Zhai, Quan-Guo [1 ]
Bu, Xianhui [2 ]
Feng, Pingyun [1 ]
机构
[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA
关键词
HIGHLY SELECTIVE SEPARATION; HIGH PROTON CONDUCTIVITY; EFFICIENT; LIGAND;
D O I
10.1039/c5dt02861b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
By using the same ligand, 2,5-furandicarboxylic acid (FDA), and varying synthetic conditions (especially the In3+/FDA ratio), it is possible to access three unique building blocks of indium, demonstrating charge-switching from a positive trimer to a negative monomer and leading to the synthesis of In-MOFs with tunable framework charge.
引用
收藏
页码:16671 / 16674
页数:4
相关论文
共 50 条
  • [41] Assembly of metal-organic frameworks (MOFs) based on indium-trimer building blocks: A porous MOF with soc topology and high hydrogen storage
    Liu, Yunling
    Eubank, Jarrod F.
    Cairns, Amy J.
    Eckert, Juergen
    Kravtsov, Victor Ch.
    Luebke, Ryan
    Eddaoudi, Mohamed
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (18) : 3278 - 3283
  • [42] Highly selective and sensitive dual-fluorescent probe for cationic Pb2+ and anionic Cr2O72-, CrO42- contaminants via a powerful indium-organic framework
    Li, Qing
    Guan, Bin-Bin
    Zhu, Wei
    Liu, Tian-Hui
    Chen, Ling-Hui
    Wang, Ya
    Xue, Dong-Xu
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2020, 291
  • [43] Heterometallic Organic Frameworks Built from Trinuclear Indium and Cuprous Halide Clusters: Ligand-Oriented Assemblies and Iodine Adsorption Behavior
    Liu, Jin-Hua
    Qi, Yan-Jie
    Zhao, Dan
    Li, Hao-Hong
    Zheng, Shou-Tian
    [J]. INORGANIC CHEMISTRY, 2019, 58 (01) : 516 - 523
  • [44] Reversible Redox Activity in Multicomponent Metal-Organic Frameworks Constructed from Trinuclear Copper Pyrazolate Building Blocks
    Tu, Binbin
    Pang, Qingqing
    Xu, Huoshu
    Li, Xiaomin
    Wang, Yulin
    Ma, Zhen
    Weng, Linhong
    Li, Qiaowei
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (23) : 7998 - 8007
  • [45] New photochromic hybrid organic-inorganic materials built from well-defined nano-building blocks
    Ribot, F
    Lafuma, A
    Eychenne-Baron, C
    Sanchez, C
    [J]. ADVANCED MATERIALS, 2002, 14 (20) : 1496 - +
  • [46] Mechanistic Insight into Hydrogen-Bond-Controlled Crystallinity and Adsorption Property of Covalent Organic Frameworks from Flexible Building Blocks
    Guo, Xinghua
    Tian, Yin
    Zhang, Meicheng
    Li, Yang
    Wen, Rui
    Li, Xing
    Li, Xiaofeng
    Xue, Ying
    Ma, Lijian
    Xia, Chuanqin
    Li, Shoujian
    [J]. CHEMISTRY OF MATERIALS, 2018, 30 (07) : 2299 - 2308
  • [47] Zwitterionic adsorbents derived from self-Exfoliated ionic covalent organic frameworks for efficient Co-Removal of anionic and cationic radionuclides
    Ouyang, Zhengdong
    Li, Xiaofeng
    Zhang, Jie
    Li, Bo
    Long, Honghan
    Zhang, Yingdan
    Yu, Kaifu
    Li, Yang
    Ma, Lijian
    [J]. CHEMICAL ENGINEERING JOURNAL, 2024, 497
  • [48] Tailor-Made Metal-Organic Frameworks from Functionalized Molecular Building Blocks and Length-Adjustable Organic Linkers by Stepwise Synthesis
    Lan, Ya-Qian
    Li, Shun-Li
    Jiang, Hai-Long
    Xu, Qiang
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (26) : 8076 - 8083
  • [49] Porous Anionic, Cationic, and Neutral Metal-Carboxylate Frameworks Constructed from Flexible Tetrapodal Ligands: Syntheses, Structures, Ion-Exchanges, and Magnetic Properties
    Liu, Tian-Fu
    Lue, Jian
    Tian, Chongbin
    Cao, Minna
    Lin, Zujin
    Cao, Rong
    [J]. INORGANIC CHEMISTRY, 2011, 50 (06) : 2264 - 2271
  • [50] A rare 4-fold interpenetrated metal-organic framework constructed from an anionic indium-based node and a cationic dicopper linker
    Pappuru, Sreenath
    Idrees, Karam B.
    Chen, Zhijie
    Shpasser, Dina
    Gazit, Oz M.
    [J]. DALTON TRANSACTIONS, 2021, 50 (19) : 6631 - 6636