Charge-tunable indium-organic frameworks built from cationic, anionic, and neutral building blocks

被引:40
|
作者
Bu, Fei [1 ]
Lin, Qipu [1 ]
Zhai, Quan-Guo [1 ]
Bu, Xianhui [2 ]
Feng, Pingyun [1 ]
机构
[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA
关键词
HIGHLY SELECTIVE SEPARATION; HIGH PROTON CONDUCTIVITY; EFFICIENT; LIGAND;
D O I
10.1039/c5dt02861b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
By using the same ligand, 2,5-furandicarboxylic acid (FDA), and varying synthetic conditions (especially the In3+/FDA ratio), it is possible to access three unique building blocks of indium, demonstrating charge-switching from a positive trimer to a negative monomer and leading to the synthesis of In-MOFs with tunable framework charge.
引用
收藏
页码:16671 / 16674
页数:4
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