Hyperfine structure of the J=1 ← 0 transition of H35Cl and H37Cl:: improved ground state parameters

被引：33

作者：

Cazzoli, G ^{[1
]}

Puzzarini, C ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2004年 / 226卷 / 02期

关键词：

lamb-dip; rotational spectrum; hyperfine structure; HCl;

D O I：

10.1016/j.jms.2004.03.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The pure rotational J = 1 <-- 0 transitions of (HCl)-Cl-35 and (HCl)-Cl-37 have been observed in the millimeter-wave region using the Lamb-dip technique to resolve the hyperfine structure due to Cl-35 or Cl-37 and H. The present observations allow to provide not only very accurate hyperfine constants but also, joint together with previous data, the most accurate ground state rotational parameters known up to now. The experimental determination of the hyperfine parameters has also been supported by ab initio computations. (C) 2004 Published by Elsevier Inc.

引用

页码：161 / 168

页数：8

共 50 条

[41] State-to-state dynamics of the Cl(2P)+C2H6(5,1=0,1)HCl(v, j)+C2H5 hydrogen abstraction reactions
Corchado, Jose C.
Chamorro, Moises G.
Rangel, Cipriano
Espinosa-Garcia, Joaquin
THEORETICAL CHEMISTRY ACCOUNTS, 2019, 138 (02)
[42] Optical-optical double resonance study of the H′ 1 (1D2) ion-pair state of I35Cl: Rovibrational structure and electronic transition dipole moment function
Hoshino, Shoma
Yamamoto, Oji
Sakamoto, Aoi
Shibuya, Kosuke
Tsukiyama, Koichi
JOURNAL OF MOLECULAR SPECTROSCOPY, 2022, 387
[43] Ab initio quantum scattering calculations and a new potential energy surface for the HCl(X1Σ+)-O2(X3Σg-) system: Collision-induced line shape parameters for O2-perturbed R(0) 0-0 line in H35Cl
Olejnik, Artur
Jozwiak, Hubert
Gancewski, Maciej
Quintas-Sanchez, Ernesto
Dawes, Richard
Wcislo, Piotr
JOURNAL OF CHEMICAL PHYSICS, 2023, 159 (13):
[44] Crystal structure of 1-butyl-3-cyclododecyloxymethylimidazolium chloride monohydrate, (C20H37N2O)Cl • H2O
Krolikowska, M.
Skrzypczak, A.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2006, 221 (02): : 155 - 156
[45] The transition probabilities from the ground state to the excited J=0 1Σu+ levels of H2: Measurements and ab initio quantum defect study
Glass-Maujean, M.
Jungen, Ch.
Schmoranzer, H.
Haar, I.
Knie, A.
Reiss, P.
Ehresmann, A.
JOURNAL OF CHEMICAL PHYSICS, 2011, 135 (14):
[46] LINESTRENGTHS IN THE 3-0 VIBRATION-ROTATIONAL BAND OF GASEOUS (HCL)-H-1-CL-35 AND THE ELECTRIC-DIPOLE MOMENT FUNCTION
OGILVIE, JF
LEE, YP
CHEMICAL PHYSICS LETTERS, 1989, 159 (2-3) : 239 - 243
[47] 35Cl NQR and structural studies on substituted amides, XyC6H5-yNHCOR (X = H or Cl; y = 0, 1 or 2 and R = C(CH3)3, CHClCH3, C6H5 or 2-ClC6H4)
Gowda, BT
Jyothi, K
Paulus, H
Fuess, H
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 2003, 58 (04): : 225 - 230
[48] Laser-based measurements of line strength, self- and pressure-broadening coefficients of the H35Cl R(3) absorption line in the first overtone region for pressures up to 1 MPa
P. Ortwein
W. Woiwode
S. Wagner
M. Gisi
V. Ebert
Applied Physics B, 2010, 100 : 341 - 347
[49] FOURIER-TRANSFORM AND DIODE-LASER SPECTROSCOPY OF THE NU-2-BAND AND NU-5-BAND OF (H3SICL)-CL-35 AND (H3SICL)-CL-37 NEAR 950 CM-1
BURGER, H
RAHNER, A
SCHULZ, P
DUPRE, J
GRANER, G
DAVIES, PB
STERN, DP
JOURNAL OF MOLECULAR SPECTROSCOPY, 1984, 106 (02) : 337 - 348
[50] The Lamb-dip spectrum of the J+1←J (J = 0, 1, 3-8) transitions of H13CN:: The nuclear hyperfine structure due to H, 13C, and 14N
Cazzoli, G
Puzzarini, C
JOURNAL OF MOLECULAR SPECTROSCOPY, 2005, 233 (02) : 280 - 289

← 1 2 3 4 5 →