Synthesis and NMR elucidation of four novel 2-(trimethylsilyl)ethyl glycosides

被引：2

作者：

Qu, Huanhuan ^{[1
,2
]}

Sun, Wenji ^{[2
]}

Zhang, Yanyan ^{[1
]}

Sollogoub, Matthieu ^{[1
]}

Zhang, Yongmin ^{[1
]}

机构：

[1] Univ Paris 06, CNRS, Inst Parisien Chim Mol, UMR 7201, F-75005 Paris, France

[2] NW Univ Xian, Biomed Key Lab Shaanxi Prov, Xian 710069, Peoples R China

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2014年 / 40卷 / 04期

关键词：

Total synthesis; Structure elucidation; Glycosides; NMR spectroscopy; Oligosaccharides; CHEMICAL-SYNTHESIS; GLYCOSYLATION; OLIGOSACCHARIDES; TRANSFORMATION;

D O I：

10.1007/s11164-013-1060-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four novel 2-(trimethylsilyl)ethyl glycosides have been synthesized by a short and efficient route starting from d-glucose. Their structures were elucidated by applying high-resolution mass spectra, and one-dimensional and two-dimensional NMR techniques. These glycosides were prepared and used as intermediate building blocks in the scheme developed for oligosaccharide construction.

引用

页码：1557 / 1564

页数：8

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