catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydroxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]

被引：0
|
作者：
Tachibana, Yuya [1 ]
Maeda, Yasukatsu [1 ]
机构：
[1] Ind Technol Ctr Wakayama Prefecture, Wakayama 6496261, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536809021394
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the polymeric title compound, [Na(2)(C(20)H(13)O(5)P)(C(2)H(6)O)(H(2)O)(5)](n), consists of two Na(I) ions, one 2'-hydroxy-1,1'-binaphthyl-2-yl phosphate anion, one ethanol ligand and five water molecules of crysallization. Each Na(I) ion has a distorted octahedral coordination geometry. The phosphate anion coordinates to one Na(I) ion and the ethanol molecule coordinates to the other. The five water molecules bridge the Na(I) ions, forming an inorganic chain structure along the b axis. The chains are connected by O-H center dot center dot center dot O hydrogen bonds into an organic-inorganic hybrid layer parallel to (001).
引用
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页码：M753 / U633
页数：14
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