catena-Poly[[diiodozinc(II)]-μ-4,4′-bipyridine-κ2N:N′]

被引：4
|
作者：
Fan, L. -Q. [1 ]
Wu, J. -H. [1 ]
机构：
[1] Huaqiao Univ, Inst Mat Phys Chem, Fujian 362021, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷 / 11期
关键词：
D O I：
10.1107/S0108270106039965
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [ ZnI2( bipy)] n ( bipy is 4,4'-bipyridine, C10H8N2), has been prepared by the hydrothermal reaction of ZnI2 and bipy at 433 K. Each Zn atom is coordinated by two N atoms from two different bipy ligands and by two I atoms in a distorted tetrahedral geometry, with Zn - N distances ranging from 2.068 ( 7) to 2.101 ( 8) angstrom and Zn - I distances ranging from 2.5471 ( 13) to 2.5673 ( 13) angstrom. The molecular structure features a zigzag polymeric chain. Face- to- face pi-pi stacking interactions between adjacent bipy ligands stabilize the structure.
引用
收藏
页码：M548 / M549
页数：2
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