Palladium nanoparticles catalyzed Sonogashira reactions for the one-pot synthesis of symmetrical and unsymmetrical diarylacetylenes

被引：19
|
作者：
Mandali, Pavan Kumar [1 ]
Chand, Dillip Kumar [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
来源：
CATALYSIS COMMUNICATIONS | 2014年 / 47卷
关键词：
Sonogashira reactions; Palladium nanoparticles; Trimethylsilylacetylene; Diarylacetylenes; METAL-ORGANIC FRAMEWORKS; CROSS-COUPLING REACTIONS; HIGHLY-ACTIVE CATALYSTS; ARYL IODIDES; FACILE SYNTHESIS; HECK REACTIONS; EFFICIENT; DIARYLALKYNES; CARBON; ALKYNYLSILANES;
D O I：
10.1016/j.catcom.2013.12.029
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A variety of symmetrical and unsymmetrical diarylacetylenes are synthesized by ligand-free palladium nanoparticles catalyzed copper-free and amine-free Sonogashira cross-coupling reactions between aryl iodides and trimethylsilylacetylene (TMSA) under mild reaction conditions. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：40 / 44
页数：5
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