catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate]

被引：1
|
作者：
Li, Xiao-Yan [1 ]
Han, Yin-Feng [1 ]
Li, Ji-Kun [2 ]
机构：
[1] Taishan Univ, Dept Chem, Taishan 271000, Shandong, Peoples R China
[2] Taishan Univ, Dept Mat Sci & Chem Engn, Tai An 271021, Shandong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536809005571
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, {[Zn(C7H7O2)(2)-(C10H8N2)]center dot 4H(2)O}(n), contains a highly distorted octahedral Zn-II metal center strongly coordinated by two N atoms of two 4,4'-bipyridine (4,4'-bipy) ligands and chelated by two 4-methylbenzoate anions. The crystallographic inversion center and glide plane present at the center of the C-C single bond of 4,4'-bipy, along with the cis coordination motif of the 4,4'-bipy, lead to one-dimensional zigzag chains. There are a large number of water molecules in the crystal structure, which also form one-dimensional chains through O-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：M354 / U1082
页数：10
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