Influence of the ZnS precursor thickness on high efficiency CU2ZnSn(S,Se)4 thin-film solar cells grown by stacked-sputtering and selenization process

被引:0
|
作者
Kim, Gee Yeong [1 ]
Son, Dae-Ho [2 ]
Nguyen, Trang Thi Thu [1 ]
Yoon, Seokhyun [1 ]
Kwon, Minsu [3 ]
Jeon, Chan-Wook [3 ]
Kim, Dae-Hwan [2 ]
Kang, Jin-Kyu [2 ]
Jo, William [1 ]
机构
[1] Ewha Womans Univ, Dept Phys, Seoul 120750, South Korea
[2] Daegu Gyeongbuk Inst Sci & Technol, Adv Convergence Res Ctr, Daegu 711873, South Korea
[3] Yeungnam Univ, Dept Chem Engn, Gyongsan 712749, South Korea
关键词
Cu2ZnSn(S; Se)(4); Kelvin probe force microscopy; Depth profile; Secondary phase; Raman spectroscopy; and photo conversion efficiency; RAMAN-SCATTERING;
D O I
暂无
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
CZTSSe thin-films were deposited by stacked sputtering methods (ZnS/SnS/Cu) and annealed with selenization. We adjusted the thickness of the ZnS precursor layer in CZT precursors. A 337 nm thickness of ZnS precursor was shown an efficiency of up to 9.1%. We investigated the secondary phases by Raman spectroscopy and Kelvin probe force microscopy with depth profiles. The Cu2SnSe3, ZnSe, and MoSe2 secondary phases appeared near the back contact region. The phase distributions of the CZTSSe thin-films are different depending on ZnS precursor thickness with different depths. This phase characterization can describe the influences to the device performance of the CZTSSe thin-film solar cells.
引用
收藏
页数:3
相关论文
共 50 条
  • [21] Solution-Processed Cu2ZnSn(S, Se)4 Thin Film Solar Cells
    Cui G.
    Yang Y.
    Li Y.
    Wang Y.
    Zhu C.
    [J]. Kuei Suan Jen Hsueh Pao/Journal of the Chinese Ceramic Society, 2021, 49 (03): : 483 - 494
  • [22] Cu2ZnSn(S,Se)4 thin film solar cells using printing and high-pressure sintering process
    Gao, Feng
    Maeda, Tsuyoshi
    Wada, Takahiro
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS, 2014, 53 (04)
  • [23] Cu2ZnSn(S,Se)4 thin film solar cells fabricated with benign solvents
    Zhang C.
    Zhong J.
    Tang J.
    [J]. Frontiers of Optoelectronics, 2015, 8 (3) : 252 - 268
  • [24] 10% Efficiency Cu2ZnSn(S,Se)4 thin film solar cells fabricated by magnetron sputtering with enlarged depletion region width
    Li, Jianjun
    Wang, Hongxia
    Luo, Miao
    Tang, Jiang
    Chen, Cheng
    Liu, Wei
    Liu, Fangfang
    Sun, Yun
    Han, Junbo
    Zhang, Yi
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2016, 149 : 242 - 249
  • [25] Optimization of the Selenization Pressure Enabling Efficient Cu2ZnSn(S,Se)4 Solar Cells
    Guo, Hongling
    Meng, Rutao
    Hu, Long
    Lin, Chun-Ho
    Sun, Yali
    Liu, Yue
    Wu, Jianyu
    Shen, Zhan
    Chu, Dewei
    Wang, Gang
    Wu, Li
    Liang, Guangxing
    Xiong, Shifu
    Liu, Fangfang
    Zhang, Yi
    Wu, Tom
    [J]. SOLAR RRL, 2022, 6 (01):
  • [26] Correlating Molecular Precursor Interactions with Device Performance in Solution-Processed Cu2ZnSn(S,Se)4 Thin-Film Solar Cells
    Agbenyeke, Raphael
    Sheppard, Alice
    Keynon, Jacques
    Benhaddou, Nada
    Fleck, Nicole
    Corsetti, Valentina
    Alkhalifah, Mohammed A.
    Tiwari, Devendra
    Bowers, Jake W.
    Fermin, David J.
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2024, 16 (27) : 35315 - 35322
  • [27] In-free thin-film solar cells: Cu2ZnSn(S,Se)4 films generated from a single molecular precursor solution
    Fermin, David
    Tiwari, Devendra
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [28] Nanoscale sharp bandgap gradient for efficiency improvement of Cu2ZnSn(S, Se)4 thin film solar cells
    Zhang, Ziqi
    Qi, Yanlong
    Zhao, Weiqiang
    Liu, Jingling
    Liu, Xinsheng
    Cheng, Ke
    Du, Zuliang
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 910
  • [29] Roughness-Controlled Cu2ZnSn(S,Se)4 Thin-Film Solar Cells with Reduced Charge Recombination
    Cheon, Ki Beom
    Hwang, Sun Kyung
    Seo, Se Won
    Park, Jae-Hyun
    Park, Min-Ah
    Kim, Jin Young
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (27) : 24088 - 24095
  • [30] Efficiency Limitation on High Efficiency Cu2ZnSn(S,Se)4 Solar Cell
    Kim, SeongYeon
    Rana, Tanka R.
    Kim, Junho
    Son, Dae-Ho
    Yang, Kee-Jeong
    Kang, Jin-Kyu
    Kim, Dae-Hwan
    [J]. 2018 IEEE 7TH WORLD CONFERENCE ON PHOTOVOLTAIC ENERGY CONVERSION (WCPEC) (A JOINT CONFERENCE OF 45TH IEEE PVSC, 28TH PVSEC & 34TH EU PVSEC), 2018, : 1909 - 1913