Analysis of the zero-field splitting parameters of Mn2+ ions doped into yttrium aluminum borate YAl3(BO3)4 single crystal: Substitution position of the impurity ion

被引：11
|
作者：
Acikgoz, Muhammed [1 ]
Gnutek, Pawel [2 ]
机构：
[1] Bahcesehir Univ, Fac Arts & Sci, TR-34353 Istanbul, Turkey
[2] West Pomeranian Univ Technol, Inst Phys, Modeling Spect Grp, PL-70310 Szczecin, Poland
来源：
OPTICAL MATERIALS | 2014年 / 36卷 / 08期
关键词：
Optical materials; Computational techniques; Crystal structure; Crystal fields; ELECTRON-PARAMAGNETIC-RESONANCE; SUPERPOSITION MODEL ANALYSIS; DIVALENT MANGANESE; ENERGY-LEVELS; SYMMETRY; LASER; CR3+; EMR; LUMINESCENCE; SPECTROSCOPY;
D O I：
10.1016/j.optmat.2014.03.021
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Substitutions options for Mn2+ doped YAl3(BO3)(4) crystal at room temperature have been analyzed in detail using a semiempirical superposition model (SPM) analysis, which enables correlation of the spectroscopic and crystallographic data. The very large zero-field splitting parameter (ZFSP) b(2)(0)(= D) for Mn2+ ion in YAl3(BO3)(4) crystal observed by electron magnetic resonance (EMR) has been interpreted in the framework of SPM. It is considered that the replacement of the Mn2+ for Al3+ induces a sizable lattice distortion, which gives rise to a large D value. It is also indicated that the zero-field splitting depends linearly on the angular distortion of the ligands around Mn2+ doped into YAl3(BO3)(4). (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：1311 / 1318
页数：8
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