New approaches to organocatalysis based on C-H and C-X bonding for electrophilic substrate activation

被引：48

作者：

Nagorny, Pavel ^{[1
]}

Sun, Zhankui ^{[2
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

[2] Shanghai Jiao Tong Univ, Sch Pharm, 800 Dongchuan Rd, Shanghai 200240, Peoples R China

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 12卷

关键词：

C-H hydrogen bond; counteranion activation; electrophile activation; halogen bond donor; hydrogen bond donor; organocatalysis; O HYDROGEN-BOND; ANION-BINDING CATALYSIS; NUCLEOPHILIC DEAROMATIZATION; ENANTIOSELECTIVE REACTIONS; TETRAALKYLAMMONIUM SALTS; CARBONYL-COMPOUNDS; BRONSTED ACID; DONORS; IODINE; PHASE;

D O I：

10.3762/bjoc.12.283

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrogen bond donor catalysis represents a rapidly growing subfield of organocatalysis. While traditional hydrogen bond donors containing N-H and O-H moieties have been effectively used for electrophile activation, activation based on other types of non-covalent interactions is less common. This mini review highlights recent progress in developing and exploring new organic catalysts for electrophile activation through the formation of C-H hydrogen bonds and C-X halogen bonds.

引用

页码：2834 / 2848

页数：15

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