Synthesis of chiral coordination polymers by spontaneous resolution

被引：67
|
作者：
Li, Feng
Li, Taohai
Li, Xiaoju
Li, Xing
Wang, Yuling
Cao, Rong [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 06期
关键词：
D O I：
10.1021/cg0600905
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three complexes have been synthesized from the reactions of 3,3-tetramethyleneglutaric acid (H(2)TMG), Cd(NO3)(2), and secondary ligands: [Cd(TMG)](n) (1), {[Cd(TMG)(1,10-phen), H2O] center dot 2H(2)O}(n) ( 2), and [Cd(TMG)(4,4'-bipy)](n) ( 3) ( phen = 1,10-phenanthroline, 4,4'- bipy = 4,4'-bipyridine). By adopting potential chiral ligands, metal-organic helical chains as a transmitter for chiral information, and coordination bonds as chiral discriminative interactions, the chiral coordination polymer 3 with an interesting three-dimensional architecture has been synthesized successfully by spontaneous resolution.
引用
收藏
页码：1458 / 1462
页数：5
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