Synthesis of chiral coordination polymers by spontaneous resolution

被引：67
|
作者：
Li, Feng
Li, Taohai
Li, Xiaoju
Li, Xing
Wang, Yuling
Cao, Rong [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 06期
关键词：
D O I：
10.1021/cg0600905
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three complexes have been synthesized from the reactions of 3,3-tetramethyleneglutaric acid (H(2)TMG), Cd(NO3)(2), and secondary ligands: [Cd(TMG)](n) (1), {[Cd(TMG)(1,10-phen), H2O] center dot 2H(2)O}(n) ( 2), and [Cd(TMG)(4,4'-bipy)](n) ( 3) ( phen = 1,10-phenanthroline, 4,4'- bipy = 4,4'-bipyridine). By adopting potential chiral ligands, metal-organic helical chains as a transmitter for chiral information, and coordination bonds as chiral discriminative interactions, the chiral coordination polymer 3 with an interesting three-dimensional architecture has been synthesized successfully by spontaneous resolution.
引用
收藏
页码：1458 / 1462
页数：5
相关论文
共 50 条
  • [1] From achiral ligands to chiral coordination polymers: Spontaneous resolution, weak ferromagnetism, and topological ferrimagnetism
    Gao, EQ
    Yue, YF
    Bai, SQ
    He, Z
    Yan, CH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (05) : 1419 - 1429
  • [2] A series of three-dimensional (3D) chiral lanthanide coordination polymers generated by spontaneous resolution
    Zhang, Li-Min
    Deng, Da-Yi
    Peng, Guo
    Sun, Lin
    Liang, Li
    Lan, Guo-Qiang
    Deng, Hong
    CRYSTENGCOMM, 2012, 14 (23): : 8083 - 8089
  • [3] Chiral 3D Coordination Polymers Consisting of Achiral Terpyridyl Precursors: from Spontaneous Resolution to Enantioenriched Induction
    Zuo, Tao
    Luo, Dong
    Huang, Yong-Liang
    Li, Yan Yan
    Zhou, Xiao-Ping
    Li, Dan
    CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (09) : 1936 - 1940
  • [4] Chiral Detection with Coordination Polymers
    Thoonen, Shannon
    Hua, Carol
    CHEMISTRY-AN ASIAN JOURNAL, 2021, 16 (08) : 890 - 901
  • [5] Resolution of chiral nitrogen atoms in 1D helical coordination polymers
    Feng, Guoqiang
    Xu, Haoxiang
    Li, Wei
    Zhang, Jie
    INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 96 : 81 - 85
  • [6] Spontaneous resolution of a chiral polyoxometalate: Synthesis, crystal structures and properties
    Cai, Lili
    Li, Yuxin
    Yu, Chaojie
    Ji, Hongmei
    Liu, Ying
    Liu, Shuxia
    INORGANICA CHIMICA ACTA, 2009, 362 (08) : 2895 - 2899
  • [7] Self-Assembly of Silver(I) and Ditopic Heteroscorpionate Ligands. Spontaneous Chiral Resolution in Helices and Sequence Isomerism in Coordination Polymers
    Dura, Gema
    Carmen Carrion, M.
    Jalon, Felix A.
    Rodriguez, Ana M.
    Manzano, Blanca R.
    CRYSTAL GROWTH & DESIGN, 2013, 13 (08) : 3275 - 3282
  • [8] Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates
    M. S. Zavakhina
    D. G. Samsonenko
    D. N. Dybtsev
    M. P. Yutkin
    A. V. Virovets
    V. P. Fedin
    Russian Chemical Bulletin, 2013, 62 : 716 - 721
  • [9] Synthesis and Investigations of Chiral NNO Type Copper(II) Coordination Polymers
    Larionov, Vladimir A.
    Yashkina, Lidiya V.
    Smol'yakov, Alexander F.
    Zubavichus, Yan V.
    Babievsky, Kirill K.
    Akat'yev, Nikolay V.
    Titov, Aleksei A.
    Belokon, Yuri N.
    Maleev, Victor I.
    CHEMISTRYSELECT, 2018, 3 (02): : 653 - 656
  • [10] Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates
    Zavakhina, M. S.
    Samsonenko, D. G.
    Dybtsev, D. N.
    Yutkin, M. P.
    Virovets, A. V.
    Fedin, V. P.
    RUSSIAN CHEMICAL BULLETIN, 2013, 62 (03) : 716 - 721
12345