Synthesis and crystal structure analysis of one dimensional supramolecular [Cd (Glu) (Tu)2]n

被引：0
|
作者：
Ke, Y
Li, J [1 ]
Zhang, Y
机构：
[1] Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2002年 / 37卷 / 05期
关键词：
cadmium; crystal; one-dimensional; structure; supramolecular; X-ray;
D O I：
10.1002/1521-4079(200205)37:5<501::AID-CRAT501>3.0.CO;2-L
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The complex of [Cd (C5H6O4) (CH4N2S)(2)](n) (I) has been synthesized and its X-ray crystal structure determined at room temperature, M = 394.74, monoclinic, space group Pc (No. 7), with lattice parameters a = 7.683(3), b = 11.566, c = 16.00(1) Angstrom, beta = 100.32(4)degrees, and Z = 4. There are two different Cd sites in this complex. Cd (1) coordinates to four oxygen atoms from Glutaric anion and two sulfide atoms from thiourea. Cd (2) coordinates to three oxygen and two sulfide atoms. The Cd atoms are linked by glutaric anion to form one-dimensional chains. The adjacent chains are held together by hydrogen bonds to form a three dimensional network.
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收藏
页码：501 / 508
页数：8
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