Comparison of the Sulfur Poisoning of PBI and Nafion PEMFC Cathodes

被引：29
|
作者：
Garsany, Yannick [1 ]
Gould, Benjamin D. [1 ]
Baturina, Olga A. [1 ]
Swider-Lyons, Karen E. [1 ]
机构：
[1] USN, Res Lab, Washington, DC 20375 USA
来源：
ELECTROCHEMICAL AND SOLID STATE LETTERS | 2009年 / 12卷 / 09期
关键词：
hydrogen compounds; polymers; proton exchange membrane fuel cells; sulphur compounds; HIGH-TEMPERATURE OPERATION; MEMBRANE FUEL-CELLS; PERFORMANCE; ACID; SO2;
D O I：
10.1149/1.3168516
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The poisoning effect of H(2)S and SO(2) in air is compared for phosphoric-acid-doped polybenzimidazole (PBI) membrane and perfluorosulfonic acid (Nafion) proton exchange membrane fuel cells (PEMFCs). The cathodes of PBI PEMFCs are about 70 times more resistant to 1 ppm of H(2)S or SO(2) than the Nafion PEMFCs. The PBI PEMFCs only lose < 2% in cell performance when exposed to 1 ppm of H(2)S or SO(2) and have 5.2 and 7.1% losses with 5 and 10 ppm H(2)S over 24 h, respectively. Purging the poisoned PBI cells with neat air leads to complete performance recovery.
引用
收藏
页码：B138 / B140
页数：3
相关论文
共 50 条
  • [21] Nanocomposite Nafion containing sulfonated particles for PEMFC application
    Bébin, P
    Caravanier, M
    Galiano, H
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U1648 - U1648
  • [22] Study of the Constrained Expansion of Nafion within the Hardware of a PEMFC
    Folgado, M. A.
    Ferreira-Aparicio, P.
    Chaparro, A. M.
    POLYMER ELECTROLYTE FUEL CELLS 14, 2014, 64 (03): : 729 - 738
  • [23] Contribution of Nafion loading to the activity of catalysts and the performance of PEMFC
    Lai, Chien-Ming
    Lin, Jing-Chie
    Ting, Fu-Ping
    Chyou, San-Der
    Hsueh, Kan-Lin
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (15) : 4132 - 4137
  • [24] Ionic conductivity of PEMFC electrodes - Effect of Nafion loading
    Li, GC
    Pickup, PG
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (11) : C745 - C752
  • [25] Nanostructured sulfur cathodes
    Yang, Yuan
    Zheng, Guangyuan
    Cui, Yi
    CHEMICAL SOCIETY REVIEWS, 2013, 42 (07) : 3018 - 3032
  • [26] THE POISONING OF OXIDE CATHODES BY GOLD
    ROTHSTEIN, J
    PHYSICAL REVIEW, 1946, 69 (11-1): : 693 - 693
  • [27] Nanotechnology for Sulfur Cathodes
    Li, Matthew
    Lu, Jun
    Amine, Khalil
    ACS NANO, 2021, 15 (05) : 8087 - 8094
  • [28] Regression Analysis of High Temperature PBI Based PEMFC Performance
    Ubong, Etim U.
    Dimitrov, Boyan
    Domadia, Aadil
    PROTON EXCHANGE MEMBRANE FUEL CELLS 9, 2009, 25 (01): : 1659 - 1668
  • [29] meta-PBI/methylated PBI-OO blend membranes for acid doped HT PEMFC
    Cho, Hyeongrae
    Hur, Eun
    Henkensmeier, Dirk
    Jeong, Gisu
    Cho, Eunae
    Kim, Hyoung Juhn
    Jang, Jong Hyun
    Lee, Kwan Young
    Hjuler, Hans Aage
    Li, Qingfeng
    Jensen, Jens Oluf
    Cleemann, Lars Nielausen
    EUROPEAN POLYMER JOURNAL, 2014, 58 : 135 - 143
  • [30] MXenes in sulfur cathodes for lithium–sulfur batteries
    Andrew Jun Yao Wong
    Wei Ying Lieu
    Hui Ying Yang
    Zhi Wei Seh
    Journal of Materials Research, 2022, 37 : 3890 - 3905
12345