Asymmetric Suzuki-Miyaura Coupling in Water with a Chiral Palladium Catalyst Supported on an Amphiphilic Resin

被引：214
|
作者：
Uozumi, Yasuhiro [1 ,2 ,3 ]
Matsuura, Yutaka [1 ,2 ]
Arakawa, Takayasu [1 ,2 ]
Yamada, Yoichi M. A. [3 ]
机构：
[1] Inst Mol Sci, Okazaki, Aichi 4448787, Japan
[2] Grad Sch Adv Studies, Okazaki, Aichi 4448787, Japan
[3] RIKEN, Wako, Saitama 3510198, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 15期
关键词：
asymmetric catalysis; biaryls; cross-coupling; heterogeneous catalysis; water; PHOSPHINE-LIGANDS; BIARYL COMPOUNDS; COMPLEX; ALKYLATION;
D O I：
10.1002/anie.200900469
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
You oughta use water: Broad functional-group (FG) tolerance was observed for the title coupling of aryl halides (X=Cl, Br, I) and aryl boronic acids to give biaryl compounds with up to 94 % ee. The chiral imidazoindole phosphine-palladium catalyst supported on an amphiphilic polystyrene- poly(ethylene glycol) (PS-PEG) resin could be recycled readily. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2708 / 2710
页数：3
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