Hydrogen storage in the giant-pore metal-organic frameworks MIL-100 and MIL-101

被引：715
|
作者：
Latroche, Michel [1 ]
Surble, Suzy
Serre, Christian
Mellot-Draznieks, Caroline
Llewellyn, Philip L.
Lee, Jin-Ho
Chang, Jong-San
Jhung, Sung Hwa
Ferey, Gerard
机构：
[1] CNRS, Lab Chim Met Terres Rares, UPR 209, F-94320 Thiais, France
[2] Univ Versailles, UMR 8180, Inst Lavoisier, F-78035 Versailles, France
[3] Univ Aix Marseille 1, CNRS, UMR 6121, Ctr St Jerome, F-13397 Marseille 20, France
[4] Korea Res Inst Chem Technol, Taejon 305600, South Korea
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 48期
关键词：
carboxylate ligands; chromium; hydrogen; mesoporous materials; physisorption;
D O I：
10.1002/anie.200600105
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Large hydrogen-storage capacity at liquid-nitrogen temperature is exhibited by the metal-organic framework MIL-101. In the zeotype architecture of this porous solid (see picture) each intersection of the cages is occupied by a supertetrahedron formed by trimers of chromium octahedra assembled with benzene-1,4-dicarboxylate ligands. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：8227 / 8231
页数：5
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