MULTIVARIATE FACTOR ASSESSMENT FOR LITHOGENIC AND ANTHROPOGENIC DISTRIBUTION OF MACRO AND TRACE ELEMENTS IN SURFACE WATER. CASE STUDY: BASIN OF THE BREGALNICA RIVER, REPUBLIC OF MACEDONIA

被引：3
|
作者：
Balabanova, Biljana [1 ]
Stafilov, Trajce [2 ]
Sajn, Robert [3 ]
Tanaselia, Claudiu [4 ]
机构：
[1] Goce Delcev Univ, Fac Agr, Krste Misirkov Bb, Stip, Macedonia
[2] Ss Cyril & Methodius Univ, Inst Chem, Fac Sci, POB 162, Skopje 1000, Macedonia
[3] Geol Survey Slovenia, Dimiceva Ul 14, Ljubljana 1000, Slovenia
[4] INCDO INOE 2000 Res Inst Analyt Instrumentat ICIA, Cluj Napoca, Romania
来源：
Macedonian Journal of Chemistry and Chemical Engineering | 2016年 / 35卷 / 02期
关键词：
heavy metals; spatial distribution; factor analysis; ICP-AES; ICP-MS; Bregalnica river; DOL ORE DISTRICT; HEAVY-METALS; COPPER MINE; SEDIMENTS; RESERVOIR; GEOCHEMISTRY; POLLUTION; VICINITY; QUALITY; INDIA;
D O I：
10.20450/mjcce.2016.899
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This study presents the spatial distribution of 69 elements in the surface water of the Bregalnica river basin. The concentration of elements was determined using inductively coupled plasma with mass spectrometry (ICP-MS) and inductively coupled plasma-atomic emission spectrometry (ICP-AES). The data summary results were reduced with the application of multivariate factor analysis, whereupon three dominant geochemical associations were obtained: Fl (Ca-K-Mg-Na-Ba-Li-Mn-Sr-V), F2 (Al-Fe) and F3 (Sb). Anthropogenic enrichments of Pb and Zn occur in the Pb-Zn mine area. The obtained data exceeded the maximum allowed concentrations in accordance with the national regulation for surface water quality. Trace elements including REEs were significantly correlated with the dominant geological formations characteristic of the different sub-regions in the investigated area.
引用
收藏
页码：235 / 250
页数：16
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