A two-step, catalytic synthesis of δ-hydroxy-γ-lactones from allylic acetates and bis(trimethylsilyl)ketene acetals

被引：14

作者：

Rudler, H

Parlier, A

Cantagrel, F

Harris, PA

Bellassoued, M

机构：

[1] Univ Paris 06, Lab Synth Organ & Organomet, UMR 7611, F-75252 Paris 5, France

[2] Univ Cergy Pontoise, CNRS, Lab Synth Organomet, F-95031 Cergy Pontoise, France

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 09期

关键词：

D O I：

10.1039/b001175o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(trimethylsilyl) ketene acetals react successively with allylic acetates, in the presence of Pd-(0) then with H2O2, in the presence of methyltrioxorhenium, to give delta-hydroxy-gamma-lactones via gamma-unsaturated carboxylic acids.

引用

页码：771 / 772

页数：2