A two-step, catalytic synthesis of δ-hydroxy-γ-lactones from allylic acetates and bis(trimethylsilyl)ketene acetals

被引：14
|
作者：
Rudler, H
Parlier, A
Cantagrel, F
Harris, PA
Bellassoued, M
机构：
[1] Univ Paris 06, Lab Synth Organ & Organomet, UMR 7611, F-75252 Paris 5, France
[2] Univ Cergy Pontoise, CNRS, Lab Synth Organomet, F-95031 Cergy Pontoise, France
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 09期
关键词：
D O I：
10.1039/b001175o
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bis(trimethylsilyl) ketene acetals react successively with allylic acetates, in the presence of Pd-(0) then with H2O2, in the presence of methyltrioxorhenium, to give delta-hydroxy-gamma-lactones via gamma-unsaturated carboxylic acids.
引用
收藏
页码：771 / 772
页数：2
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