Thermal and optical properties of Bi2O3-GeO2-B2O3 glasses

被引：0
|
作者：
Yamashita, Naoto [1 ]
Suetsugu, Tatsuya [1 ]
Einishi, Toshihiko [1 ]
Fukumi, Kohei [2 ]
Kitamura, Naoyuki [2 ]
Nishii, Junji [2 ]
机构：
[1] Isuzu Glass Co, Osaka 5570063, Japan
[2] Natl Inst Adv Ind Sci & Technol, Photon Res Inst, Osaka 5638577, Japan
来源：
PHYSICS AND CHEMISTRY OF GLASSES-EUROPEAN JOURNAL OF GLASS SCIENCE AND TECHNOLOGY PART B | 2009年 / 50卷 / 04期
关键词：
BORATE GLASSES; SYSTEM; RAMAN; GRATINGS;
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The thermal and optical properties of Bi2O3-GeO2-B2O3 glasses have been studied. The glass transition and deformation temperatures have a maximum at a Bi2O3 content of similar to 20 mol%. The molar refraction shout's additivity with composition, decreases linearly with decreasing Bi2O3 content and does not depend on the B2O3/GeO2 ratio. Colourless glasses were obtained in a low Bi2O3, high GeO2 region of composition, as expected from electronegativity. Raman scattering spectroscopy showed that the glass structure depends on the Bi2O3/B2O3 ratio and on GeO2 content. By a glass imprinting method, a one-dimensional periodic pattern with a period of 500 nm was successfully fabricated on the glass surface.
引用
收藏
页码：257 / 261
页数：5
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