Evaluation of PCDD/Fs emission from fluidized bed incinerators co-firing MSW with coal in China

被引:101
|
作者
Yan, J. H. [1 ]
Chen, T. [1 ]
Li, X. D. [1 ]
Zhang, J. [1 ]
Lu, S. Y. [1 ]
Ni, M. J. [1 ]
Cen, K. F. [1 ]
机构
[1] Zhejiang Univ, Inst Thermal Power Engn, State Key Lab Clean Energy Utilizat, Zhejiang 310027, Peoples R China
关键词
polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs); fluidized bed incinerator (FBI); municipal solid waste (MSW); coal;
D O I
10.1016/j.jhazmat.2005.12.007
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The levels and homologue profile of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) front stack gas of three typical fluidized bed incinerators co-firing municipal solid waste (MSW) with Chinese coal were measured. The PCDD/Fs emission was in the range of 0.0054-0.1961 ng I-TEQ/N m(3). Comparison of PCDD/Fs detection results by HRGC/HRMS and HRGC/LRMS suggested that it was feasible to detect fly ash with high PCDD/Fs concentration by HRGC/LRMS. Several factors on PCDD/Fs emission were discussed. The primary reason for the lower PCDD/Fs emission was the inhibition mechanism of relatively high sulfur in feeding coal on PCDD/Fs formation. The emission results also showed that there was no directly correlation between PCDD/Fs levels and CO. O-2 and HCl concentration in flue gas. It was estimated that about 0.1034 I-TEQ was annually emitted to atmosphere from the tested three MSW incinerators (total daily treatment capacity is 800 tonnes MSW). (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:47 / 51
页数:5
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