Selective CO oxidation over ceria supported CuO catalysts

被引：34
|
作者：
Derekaya, Filiz Balikci [1 ]
Kutar, Cenk [2 ]
Guldur, Cigdem [2 ]
机构：
[1] Gazi Univ, Inst Sci & Technol, Dept Adv Technol, TR-06570 Maltepe, Turkey
[2] Gazi Univ, Fac Engn & Architecture, Dept Chem Engn, TR-06570 Maltepe, Turkey
来源：
MATERIALS CHEMISTRY AND PHYSICS | 2009年 / 115卷 / 2-3期
关键词：
CuO-CeO2; Selective CO oxidation; Catalysis; PREFERENTIAL OXIDATION; CARBON-MONOXIDE; CUO-CEO2; CATALYSTS; EXCESS HYDROGEN; TEMPERATURE; CUO/CEO2; REMOVAL; GAS; H-2;
D O I：
10.1016/j.matchemphys.2009.01.005
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The effect of preparation method and pretreatment on the characteristic properties and selective CO oxidation activities of 50/50 CuO/CeO2, 25/25/50 CuO/Co3O4/CeO2 and 5/95 CuO/CeO2 catalysts was investigated. Catalysts were characterized by BET surface area measurement, N-2 physisorption, SEM micrographs and X-ray diffraction. The selective oxidation reaction in H-2 rich stream was carried out between the 110 degrees C and 210 degrees C temperatures. The 5/95 CuO/CeO2 catalysts gave the best CO conversion and selectivity result. The 5/95 CuO/CeO2 catalyst calcined at 700 degrees C protected its activity and selectivity at 200 degrees C during 24 h. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：496 / 501
页数：6
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