Microwave-assisted clean synthesis of 6-aryl-2,4-diamino-1,3,5-triazines in [bmim][PF6]

被引：35
|
作者：
Peng, YQ [1 ]
Song, GH [1 ]
机构：
[1] E China Univ Sci & Technol, Inst Pesticides & Pharmaceut, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 27期
基金：
中国国家自然科学基金;
关键词：
clean synthesis; ionic liquids; microwave; triazines;
D O I：
10.1016/j.tetlet.2004.04.195
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient and green approach was developed to prepare 6-aryl-2,4-diamino-1,3,5-triazines from corresponding arylnitriles and dicyanodiamide in ionic liquid [bmim][PF6] under computer-controlled microwave irradiation. Particularly valuable features of this method included the short reaction time, good yield, convenient operation and eco-friendly solvent. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5313 / 5316
页数：4
相关论文
共 50 条
  • [21] *DERIVATY 6-AMINOMETHYL-2,4-DIAMINO-1,3,5-TRIAZINU
    ETTEL, V
    NOSEK, J
    CHEMICKE LISTY, 1952, 46 (05): : 289 - 292
  • [22] SYNTHESIS OF N-SUBSTITUTED 2,4-DIAMINO-6-ALKYL-1,3,5-TRIAZINES CONTAINING LONG ALKYL RADICALS
    KELAREV, VI
    BELLUL, M
    ZAVYALOV, VI
    DIBI, A
    GOLOVIN, AN
    LISITSYN, EA
    KARAKHANOV, RA
    ZHURNAL ORGANICHESKOI KHIMII, 1988, 24 (05): : 1100 - 1105
  • [23] Hybrid Molecules Composed of 2,4-Diamino-1,3,5-triazines and 2-Imino-Coumarins and Coumarins. Synthesis and Cytotoxic Properties
    Makowska, Anna
    Saczewski, Franciszek
    Bednarski, Patrick J.
    Saczewski, Jaroslaw
    Balewski, Lukasz
    MOLECULES, 2018, 23 (07):
  • [24] Expanding the Landscape of Dual Action Antifolate Antibacterials through 2,4-Diamino-1,6-dihydro-1,3,5-triazines
    Georgiades, John D.
    Berkovich, Daniel A.
    Mckee, Samuel R.
    Smith, Angela R.
    Sankaran, Banumathi
    Flentie, Kelly N.
    Castaneda, Carlos H.
    Grohmann, Daniel G.
    Rohatgi, Ram
    Lasky, Carrie
    Mason, Twila A.
    Champine, James E.
    Miller, Patricia A.
    Moellmann, Ute
    Moraski, Garrett C.
    Franzblau, Scott G.
    Miller, Marvin J.
    Stallings, Christina L.
    Jez, Joseph M.
    Hathaway, Bruce A.
    Wencewicz, Timothy A.
    ACS INFECTIOUS DISEASES, 2025, 11 (03): : 689 - 702
  • [25] Synthesis of 6-aryl-2,4-diamino-pyrimidines and triazines using palladium catalysed Suzuki cross-coupling reactions
    Cooke, G
    de Cremiers, HA
    Rotello, VM
    Tarbit, B
    Vanderstraeten, PE
    TETRAHEDRON, 2001, 57 (14) : 2787 - 2789
  • [26] TRICHOMONACIDAL DRUGS .6. 2,4-DICHLORO DERIVATIVES OF THE PIPERIDINO-1,3,5-TRIAZINES AND PIPERAZINYL-1,3,5-TRIAZINES
    KREUTZBERGER, A
    KOCHANOWSKI, R
    ARZNEIMITTEL-FORSCHUNG/DRUG RESEARCH, 1987, 37-2 (09): : 999 - 1002
  • [27] High yielding microwave-assisted synthesis of tri-substituted 1,3,5-triazines using Pd-catalyzed aryl and heteroarylamination
    Dao, Pascal
    Garbay, Christiane
    Chen, Huixiong
    TETRAHEDRON, 2012, 68 (20) : 3856 - 3860
  • [28] Acid-Base Properties and Complex Formation of 2,4-Diamino-6-(Carbamoylmethylsulphinyl)-1,3,5-Triazines
    Salnikov, Yu., I
    Boos, G. A.
    Fattakhov, S. G.
    Shulaeva, M. M.
    Chmutova, G. A.
    Khusainova, A. R.
    Neklyudov, V. V.
    UCHENYE ZAPISKI KAZANSKOGO UNIVERSITETA-SERIYA ESTESTVENNYE NAUKI, 2011, 153 (03): : 48 - 60
  • [29] SUBSTITUENT EFFECT IN THE HYDROXYMETHYLATION OF 6-SUBSTITUTED-2,4-DIAMINO-1,3,5-TRIAZINE
    SATO, K
    MARUYAMA, K
    NIPPON KAGAKU KAISHI, 1993, (04) : 375 - 379
  • [30] Microwave-Assisted Synthesis of Tri-Substituted 1,3,5-Triazines from Metformin Using Benzotriazole Chemistry
    Panda, Siva S.
    Thomas, Eyana
    Pham, Ashley M.
    REACTIONS, 2022, 3 (04): : 516 - 524
12345