Asymmetric synthesis of 4-aryl-1,2,5-thiadiazolidin-3-one 1,1-dioxides via Pd-catalyzed hydrogenation of cyclic ketimines

被引：3

作者：

Zhu, Zhou-Hao ^{[1
]}

Chen, Meng-Lin ^{[1
]}

Jiang, Guo-Fang ^{[1
]}

机构：

[1] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2017年 / 15卷 / 06期

基金：

中国国家自然科学基金;

关键词：

HIGHLY ENANTIOSELECTIVE SYNTHESIS; AMINO-ACID DERIVATIVES; CHIRAL SULFAHYDANTOINS; CONJUGATE REDUCTION; SWEETENING AGENTS; KETONES; CHEMISTRY; PHOSPHONATES; ARYLATION; LIGANDS;

D O I：

10.1039/c6ob02655a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient access to optically active sulfahydantoins, 4-aryl-1,2,5-thiadiazolidin-3-one 1,1-dioxides, was developed through palladium-catalyzed asymmetric hydrogenation of the corresponding cyclic N-sulfonylketimines with up to 98% ee.

引用

页码：1325 / 1328

页数：4

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