Kinetics and mechanism of N-chloromethylamine decomposition in solutions

被引：0
|
作者：
Kuznetsov, V. V. [1 ]
Vedenyapina, M. D. [1 ,2 ]
Pleshchev, M. I. [1 ]
Gashev, S. B. [1 ]
Makhova, N. N. [1 ]
Vedenyapin, A. A. [1 ,2 ]
机构：
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
[2] Moscow Technol Inst, Moscow 117292, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2016年 / 90卷 / 03期
关键词：
N-chloromethylamine; kinetics and mechanism of decomposition; stability of N-chloromethylamine; AMINES; PH; 1,2,3-TRIALKYLDIAZIRIDINES; CHLOROALKYLAMINES; DIAZIRIDINES; CHLORAMINES; ACTIVATION; AMINATION; AMIDES;
D O I：
10.1134/S0036024416030225
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Kinetics of N-chloromethylamine decomposition in an aqueous base medium and chloroform at different temperatures is studied. The decomposition of N-chloromethylamine is found to obey a second order equation in an aqueous base medium at an equimolar ratio of the reagents and a first order equation in chloroform with excess base. The activation energy of N-chloromethylamine decomposition in the both solvents is determined. A mechanism for the reaction is proposed. N-Chloromethylamine is shown to have approximately equal stability in these solvents within the studied temperature range.
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页码：541 / 544
页数：4
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