Kinetics and mechanism of N-chloromethylamine decomposition in solutions

被引：0

作者：

Kuznetsov, V. V. ^{[1
]}

Vedenyapina, M. D. ^{[1
,2
]}

Pleshchev, M. I. ^{[1
]}

Gashev, S. B. ^{[1
]}

Makhova, N. N. ^{[1
]}

Vedenyapin, A. A. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

[2] Moscow Technol Inst, Moscow 117292, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2016年 / 90卷 / 03期

关键词：

N-chloromethylamine; kinetics and mechanism of decomposition; stability of N-chloromethylamine; AMINES; PH; 1,2,3-TRIALKYLDIAZIRIDINES; CHLOROALKYLAMINES; DIAZIRIDINES; CHLORAMINES; ACTIVATION; AMINATION; AMIDES;

D O I：

10.1134/S0036024416030225

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kinetics of N-chloromethylamine decomposition in an aqueous base medium and chloroform at different temperatures is studied. The decomposition of N-chloromethylamine is found to obey a second order equation in an aqueous base medium at an equimolar ratio of the reagents and a first order equation in chloroform with excess base. The activation energy of N-chloromethylamine decomposition in the both solvents is determined. A mechanism for the reaction is proposed. N-Chloromethylamine is shown to have approximately equal stability in these solvents within the studied temperature range.

引用

页码：541 / 544

页数：4

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