The synthesis of a 3d-4f polynuclear metal cluster under microwave irradiation: crystal structure and magnetic property of [La3Ni6(IDA)6(OH)6(H2O)12]•3NO3•15H2O (IDA = iminodiacetate)

被引：26
|
作者：
Zhuang, Gui-Lin
Sun, Xiao-Jun
Long, La-Sheng [1 ]
Huang, Rong-Bin
Zheng, Lan-Sun
机构：
[1] Xiamen Univ, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
来源：
DALTON TRANSACTIONS | 2009年 / 24期
关键词：
SINGLE-MOLECULE MAGNETS; TRIGONAL PRISMATIC CLUSTERS; IONS; LN; COMPLEX; LA; SPECTRA; SERIES; WHEEL;
D O I：
10.1039/b823294f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A cage-shaped 3d-4f heterometallic ferromagnetic cluster, consisting of six Ni(II) and three La(III) ions, was synthesized by microwave irradiation. Themagnetic susceptibilities of the cluster were fitted with the help of the program MAGPACK, revealing that the magnetic exchange in the cluster is closely related to the coordination mode and spatial distribution between the metal ions.
引用
收藏
页码：4640 / 4642
页数：3
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