Investigation of rare earth ions adsorption properties of PP-g-AA

被引:1
|
作者
Lu, K [1 ]
Peng, HL [1 ]
Chen, DT [1 ]
Shi, N [1 ]
Xu, DF [1 ]
机构
[1] Beijing Univ, Dept Tech Phys, Beijing 100871, Peoples R China
关键词
polypropylene; electron-beam; preirradiation grafting; rare earth ions; adsorption;
D O I
10.1002/(SICI)1097-4628(20000606)76:10<1549::AID-APP8>3.0.CO;2-B
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Acrylic acid (AA) was grafted onto the powdered isotactic polypropylene (i-PP) with the electron-beam-induced preirradiation method (Chen, D.-T.; Shi, N.; Xu, D.-F. J Appl Polym Sci 1999, 73, 1357-1362). Some rare earth ions, including Sm3+, Nd3+, Eu3+, Gd3+, and Er3+,, were adsorbed onto the grafting product PP-g-AA. The properties of Sm3+ adsorbed were investigated in detail. These properties include the influences of the adsorption time, acidity, ion concentration of the solution, grafting yield of AA. onto i-PP, and temperature on the quantity and efficiency of the ion adsorption. Some kinetic and thermodynamic equilibrium constants of the adsorption were obtained in the experiments. (C) 2000 John Wiley & Sons, Inc.
引用
收藏
页码:1549 / 1553
页数:5
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