Ligand field parameters in pentaammine complexes of chromium(III) with a carbon-oxygen or phosphorus-oxygen donor

被引:0
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作者
Rajendram, CRA [1 ]
Hoggard, PE [1 ]
机构
[1] UNIV N DAKOTA,DEPT CHEM,FARGO,ND 58105
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Coordination of oxyphosphorus ligands to pentaamminechromium(III) lowers the ligand field strength of the ammines to a much greater extent than trichloroacetate. This presumably signifies a weaker metal-nitrogen bond, and may contribute to the reluctance of the amines in aminophosphonate ligands to coordinate.
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页码:61 / 63
页数:3
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