Volatile organochlorine compounds formed in the bleaching of pulp with ClO2

被引：13

作者：

Juuti, S

Vartiainen, T

Joutsenoja, P

Ruuskanen, J

机构：

[1] NATL PUBL HLTH INST,DEPT ENVIRONM HYG,FIN-70701 KUOPIO,FINLAND

[2] OY AEM LTD,FIN-70211 KUOPIO,FINLAND

来源：

CHEMOSPHERE | 1996年 / 33卷 / 03期

基金：

芬兰科学院;

关键词：

bleaching effluent; chloroform; kraft pulp; volatile organic compounds; waste water;

D O I：

10.1016/0045-6535(96)00208-1

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Volatile organochlorine compounds (VOCCs) formed during kraft pulp bleaching were determined from the bleaching effluent at the bleach plants and from waste water at the waste water treatment plants of three pulp mills means by of a purge and trap injector connected to a GC/MS. Among the seventeen VOCCs identified when ClO2 was used in pulp bleaching, chloroform constituted the major fraction and dichloroacetic acid methyl ester and 2,5-dichlorothiophene were also abundant. The formation of VOCCs was related to the use of ClO2 in bleaching, with a lower ClO2 charge yielding less VOCCs and hardly any being formed when non-chlorinated bleaching agents were used. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：437 / 448

页数：12

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