Hybrid biocomposites based on calcium phosphate mineralization of self-assembled supramolecular hydrogels

被引:134
|
作者
Schnepp, Zoe A. C. [1 ]
Gonzalez-McQuire, Rosanna [1 ]
Mann, Stephen [1 ]
机构
[1] Univ Bristol, Sch Chem, Ctr Organized Matter Chem, Bristol BS8 1TS, Avon, England
关键词
D O I
10.1002/adma.200502545
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mineralization of small-molecule-based supramolecular hydrogels with calcium phosphate produces hybrid composites comprising interconnecting networks of calcified nanofilaments (see figure). Viscoelastic hybrid gels that exhibit enhanced thermal stability, stiffness, and critical strain are formed at low mineral contents, whereas extensive mineralization generates hard macroporous replicas of the supramolecular matrix.
引用
收藏
页码:1869 / +
页数:5
相关论文
共 50 条
  • [21] Transmetalation of self-assembled, supramolecular complexes
    Carnes, Matthew E.
    Collins, Mary S.
    Johnson, Darren W.
    CHEMICAL SOCIETY REVIEWS, 2014, 43 (06) : 1825 - 1834
  • [22] Supramolecular self-assembled fullerene nanostructures
    Georgakilas, V
    Pellarini, F
    Prato, M
    Guldi, DM
    Melle-Franco, M
    Zerbetto, F
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) : 5075 - 5080
  • [23] Self-assembled dimers with supramolecular chirality
    Pop, A
    Vysotsky, MO
    Saadioui, M
    Böhmer, V
    CHEMICAL COMMUNICATIONS, 2003, (10) : 1124 - 1125
  • [24] Supramolecular Chirality in Self-Assembled Systems
    Liu, Minghua
    Zhang, Li
    Wang, Tianyu
    CHEMICAL REVIEWS, 2015, 115 (15) : 7304 - 7397
  • [25] Self-assembled supramolecular nanotube yarn
    Liu, Yaqing
    Wang, Tianyu
    Liu, Minghua
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [26] Self-Assembled Polymeric Supramolecular Frameworks
    Houbenov, Nikolay
    Haataja, Johannes S.
    Iatrou, Hermis
    Hadjichristidis, Nikos
    Ruokolainen, Janne
    Faul, Charl F. J.
    Ikkala, Olli
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (11) : 2516 - 2520
  • [27] Self-assembled supramolecular rectangles NANOTECHNOLOGY
    Telford, Mark
    MATERIALS TODAY, 2005, 8 (03) : 12 - 12
  • [28] Self-Assembled Supramolecular Nanotube Yarn
    Liu, Yaqing
    Wang, Tianyu
    Huan, Yong
    Li, Zhibo
    He, Guowei
    Liu, Minghua
    ADVANCED MATERIALS, 2013, 25 (41) : 5875 - 5879
  • [29] SELF-ASSEMBLED SUPRAMOLECULAR RIGID RODS
    KOTERA, M
    LEHN, JM
    VIGNERON, JP
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (02) : 197 - 199
  • [30] Polyethyleneimine-Polyoxometalate-Based Supramolecular Self-assembled pH-Responsive Hydrogels: Formulation and in vitro Evaluation
    Azizullah
    Haider, Ali
    Kortz, Ulrich
    Joshi, Sachin A.
    Iqbal, Jamshed
    CHEMISTRYSELECT, 2017, 2 (21): : 5905 - 5912