Cyclopropenes and methylenecyclopropanes in 1,3-dipolar cycloaddition reactions

被引：16
|
作者：
Molchanov, A. P. [1 ]
Efremova, M. M. [1 ]
Kuznetsov, M. A. [1 ]
机构：
[1] St Petersburg State Univ, Inst Chem, 26 Univ Skii Prosp, St Petersburg 198504, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2022年 / 71卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
cyclopropenes; methylenecyclopropanes; dipolar cycloaddition; nitrones; azomethine ylides; azomethine imines; carbonyl ylides; diazo compounds; FORMAL 3+3 CYCLOADDITION; C-H ACTIVATION; AZOMETHINE IMINES; REGIOSELECTIVE CYCLOADDITION; EFFICIENT SYNTHESIS; CARBONYL YLIDES; FEISTS ACID; ONE-POT; NITRONES; REACTIVITY;
D O I：
10.1007/s11172-022-3460-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The review considers the main results of the cycloaddition reactions involving cyclopropenes and methylenecyclopropanes, the compounds bearing strained three-membered rings and, respectively, endo- and exocyclic double bonds. The main attention is focused on the reactions of these compounds with 1,3-dipoles (nitrones, azomethine imines, azomethine ylides, carbonyl ylides, etc.), which gave complex heterocyclic systems with high regio- and stereoselectivity.
引用
收藏
页码：620 / 650
页数：31
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