The synthesis and spectral characterization of new Cu(II), Ni(II), Co(III), and Zn(II) complexes with Schiff base

被引:93
|
作者
Temel, H [1 ]
Ilhan, S
Sekerci, M
Ziyadanogullari, R
机构
[1] Dicle Univ, Fac Educ, TR-21010 Diyarbakir, Turkey
[2] Dicle Univ, Fac Arts & Sci, Dept Chem, TR-21010 Diyarbakir, Turkey
[3] Firat Univ, Dept Chem, Fac Arts & Sci, TR-23169 Elazig, Turkey
关键词
Schiff bases; transition metals;
D O I
10.1081/SL-120003807
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Cu(II), Ni(II), Co(III) and Zn(II) complexes with Schiff base have been prepared. Ligand is derived from condensation of 1,2-bis(p-aminophenoxy)ethane and 2-hydroxynaphthalin-1-carbaldehyde. The complexes have been characterized by elemental analyses, Lambda(M), IR, UV-VIS, H-1 NMR, C-13 NMR and magnetic measurements. The ligand is coordinated to the central metal as a tetradentade ONNO ligand. The four bonding sites are the azomethine nitrogen and aldehydic-OH groups.
引用
收藏
页码:219 / 228
页数:10
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