Reactive synthesis for porous Ti3AlC2 ceramics through TiH2, Al and graphite powders

Porous Ti3AlC2 ceramics were fabricated by reactive synthesis. The process of fabrication involved five steps: (i) the pyrolysis of stearic acid at 450 degrees C; (ii) the decomposition of TiH2 at 700 degrees C, which leads to the conversion of TiH2 to Ti; (iii) the solid liquid chemical reaction of solid Ti and molten Al at 800-1000 degrees C, which converts the mixture to Ti-Al compounds; (iv) the newly synthesized Ti-Al compounds that react with surplus Ti and graphite to form ternary carbides and TiC at 1100-1200 degrees C; and (v) reactive synthesized ternary carbides and TiC that yield porous Ti3AlC2 at 1300 degrees C. The effects of sintering temperature and Al contents on porosity, pore size and permeability of porous Ti3AlC2 ceramics were examined. The results revealed that the porosity and permeability tended to increase with reactive sintering temperature. The pore forming mechanism accompanying phase transformation was explored in this study. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.