Molecular and Crystal Structure of 2-{(E)-[(5-Chloro-2-methoxyphenyl)imino]methyl}-4-nitrophenol1

被引：4

作者：

Kaynar, Nihal Kan ^{[1
]}

Agar, Erbil ^{[2
]}

Tanak, Hasan ^{[1
]}

Sahin, Songul ^{[2
]}

Buyukgungor, Orhan ^{[3
]}

Yavuz, Metin ^{[3
]}

机构：

[1] Amasya Univ, Fac Arts & Sci, Dept Phys, TR-05100 Amasya, Turkey

[2] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Samsun, Turkey

[3] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, TR-55139 Samsun, Turkey

来源：

CRYSTALLOGRAPHY REPORTS | 2018年 / 63卷 / 03期

关键词：

SCHIFF-BASES; BIOLOGICAL-ACTIVITY; COMPLEXES;

D O I：

10.1134/S1063774518030124

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The molecular structure of the title compound, C14H11ClN2O4, was determined by single crystal X-ray diffraction. The compound crystallizes in the monoclinic sp. gr. P2(1)/c with Z = 4. The title compound, C14H11ClN2O4, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The molecule is almost planar and the dihedral angle between the planes of two aromatic ring is 2.2(1)degrees. The molecular structure is stabilized by intramolecular O-HN hydrogen bond which generates a six-membered ring. In the crystal structure, the molecules are linked together by intermolecular C-HO interactions.

引用

页码：372 / 374

页数：3

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