Hydrogen Gas Sensor Based on Nanograined Pd/α-MoO3 Belts

被引:1
|
作者
Cretu, V. [1 ]
Postica, V. [1 ]
Stoianov, D. [1 ]
Trofim, V. [1 ]
Sontea, V. [1 ]
Lupan, O. [1 ,2 ]
机构
[1] Tech Univ Moldova, Dept Microelect & Biomed Engn, Kishinev, Moldova
[2] Univ Kiel, Inst Mat Sci Funct Nanomat, Kiel, Germany
关键词
MoO3; hydrogen; gas sensor; nanostructured; mechanism; SENSING PROPERTIES; THIN-FILMS; MOO3; XPS;
D O I
10.1007/978-981-287-736-9_87
中图分类号
R318 [生物医学工程];
学科分类号
0831 ;
摘要
In this work, a simple and cost-effective method for nanostructurization of alpha-MoO3 micro-belts by using an aqueous solution of PdCl2 is reported. Obtained nanograined Pd/alpha-MoO3 belts, with 70-80 nm average diameters of nanocrystallites were integrated in sensor structures for application in hydrogen gas sensing. In dependence of method for nano-structurization, a gas response of about 2-3 at 200 degrees C operating temperature was obtained. In case of K+ doped samples, the hydrogen response was enhanced to about 7.5. To explain the obtained results, the gas sensing mechanism based on catalyst properties of Pd nanoparticles and generation of oxygen vacancies is discussed in details.
引用
收藏
页码:361 / 364
页数:4
相关论文
共 50 条
  • [11] Bifunctional potentiometric sensor based on MoO3 nanorods
    G. S. Zakharova
    N. V. Podval’naya
    Journal of Analytical Chemistry, 2013, 68 : 50 - 56
  • [12] Bifunctional potentiometric sensor based on MoO3 nanorods
    Zakharova, G. S.
    Podval'naya, N. V.
    JOURNAL OF ANALYTICAL CHEMISTRY, 2013, 68 (01) : 50 - 56
  • [13] Mo Powders Fabricated from MoO3 by Reduction in Hydrogen Gas
    Hong, Seonghoon
    Lee, Dongkyu
    Oh, Changsup
    Kil, Sangcheol
    Kim, Yongha
    KOREAN JOURNAL OF METALS AND MATERIALS, 2012, 50 (06): : 445 - 448
  • [14] High response triethylamine gas sensor based on flaky W-doped MoO3
    Chen, Xingtai
    Liu, Tao
    Yin, Xi-Tao
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2024, 129 : 691 - 698
  • [15] Conductometric triethylamine sensor based on Pd nanoparticles modified Fe doped MoO3 porous nanobelts
    Li, Jingyun
    Wang, Nan
    Yang, Xiaohong
    Li, Jiangcheng
    Xiong, Shixian
    Fu, Haitao
    An, Xizhong
    SENSORS AND ACTUATORS B-CHEMICAL, 2025, 429
  • [16] On the mechanisms of hydrogen spillover in MoO3
    Chen, Liang
    JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (06): : 1755 - 1758
  • [17] Pd on MoO3 nanoplates as small-polaron-resonant eye-readable gasochromic and electrical hydrogen sensor
    Kalanur, Shankara S.
    Yoo, Il-Han
    Seo, Hyungtak
    SENSORS AND ACTUATORS B-CHEMICAL, 2017, 247 : 357 - 365
  • [18] Colorimetric acid phosphatase sensor based on MoO3 nanozyme
    Lin, Zhen
    Zhang, Xiaomin
    Liu, Shijun
    Zheng, Linlin
    Bu, Yemei
    Deng, Haohua
    Chen, Ruiting
    Peng, Huaping
    Lin, Xinhua
    Chen, Wei
    ANALYTICA CHIMICA ACTA, 2020, 1105 : 162 - 168
  • [19] MEMS Integrated MoO3 Nanostructures based Acetone Sensor
    Dwivedi, Priyanka
    Anuroop
    Dhanekar, Saakshi
    Das, Samaresh
    2018 12TH INTERNATIONAL CONFERENCE ON SENSING TECHNOLOGY (ICST), 2018, : 17 - 19
  • [20] KINETIC-THERMAL PROCESSES OF HYDROGEN SORPTION ON PD/WO3 AND PD/MOO3 BRONZE
    SUSIC, MV
    SOLONIN, YM
    JOURNAL OF MATERIALS SCIENCE, 1989, 24 (10) : 3691 - 3698