Intramolecular addition of stabilized enolates to (η6-arene)ruthenium complexes:: Synthesis of Ru-coordinated azaspirocycles

被引：17
|
作者：
Pigge, FC [1 ]
Fang, SY [1 ]
Rath, NP [1 ]
机构：
[1] Univ Missouri, Dept Chem, St Louis, MO 63121 USA
来源：
ORGANIC LETTERS | 1999年 / 1卷 / 11期
关键词：
D O I：
10.1021/ol991123v
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] Stabilized enolates attached to, cationic (arene)(RuCp)-Cp-II complexes via an amide linkage were found to participate in nucleophilic aromatic addition reactions resulting in the formation of novel cyclohexadienyl-Ru azaspirocycles. Enolate addition to the activated arene ring was found to proceed with complete stereoselectivity.
引用
收藏
页码：1851 / 1854
页数：4
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