{[M(NH3)6][Ag4M4Sn3Se13]}∞ (M=Zn, Mn): Three-dimensional chalcogenide frameworks constructed from quaternary metal selenide clusters with two different transition metals

被引：18
|
作者：
Xiong, Wei-Wei [1 ]
Miao, Jianwei [2 ]
Li, Pei-Zhou [3 ]
Zhao, Yanli [3 ]
Liu, Bin [2 ]
Zhang, Qichun [1 ]
机构：
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[2] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore
[3] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2014年 / 218卷
关键词：
Chalcogenides; Quaternary; Clusters; Photoactive; Photoelectrochemical cell; IONIC LIQUIDS; SULFIDE; SEMICONDUCTOR; CHEMISTRY; TERNARY; ORGANIZATION; SYNTHESIZE; CATION;
D O I：
10.1016/j.jssc.2014.06.035
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Herein we report solvothermal syntheses of two new three-dimensional chalcogenide frameworks {[M (NH3)(6)][Ag4M4Sn3Se13]}(n) (M=Zn (1), Mn (2)), which consist of quaternary metal selenide clusters with two different transition metals. The compounds represent the first Ag-Zn/Mn-Sn-Se based quaternary anionic frameworks. The optical studies show that the band gaps for 1 and 2 are 2.09 eV and 1.71 eV, respectively. Moreover, the photoelectrochemical study indicates that compound I displays n-type semiconducting behaviour and is photoactive under visible light illumination (lambda > 400 nm). (C) 2014 Elsevier Inc. All rights reserved.
引用
收藏
页码：146 / 150
页数：5
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